Stable Isotopes - Deuterium - D/H
Abundance –
1H = 99.985 % atom
2H (D) = 0.015 % atom
3H (T) = 10-16 % atom (radioactive, analysed at the GNS Tritium Lab)
Gas analysed –
H2
Recommended Scale –
VSMOW (Standard Mean Ocean Water, absolute isotope ratio (155.76 ± 0.05) x 10-6 [Hagemann et al., 1970])
Equipment –
Europa Geo 20-20 dual inlet for H2 gas samples derived from rock samples
Europa Geo 20-20 continuous flow coupled with CSIA-GC for various gas and liquid samples
GVI Isoprime coupled with PyrOH for water samples
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Precision‰ |
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Preferred |
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Minimum |
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Price |
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samples |
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sample |
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size |
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size |
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| SOLIDS |
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| D |
hydrosilicates |
5 |
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100mg |
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50mg |
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| LIQUIDS |
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| D |
water |
1 |
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2ml |
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0.5ml |
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| D & 18O |
water |
1.0 & 0.1 |
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5ml |
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1ml |
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| GAS |
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| D |
hydrogen |
1 |
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5ml STP* |
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1ml STP* |
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| D |
methane |
3 |
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5ml STP* |
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1ml STP* |
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| D & 13C |
methane |
3 & 1 |
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10ml STP* |
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2ml STP* |
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| *Standard Temperature and Pressure |
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